Carrier Multiplication in Quantum Dots @ Colorado School of Mines

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Author(s):

Zhibin Lin, Alberto Franceschetti (NREL), and Mark Lusk, Renewable Energy MRSEC, NSF DMR-0820518

It has been proposed that quantum mechanical effects might be used to enhance the generation of more than one electron-hole pair from a single photon in semiconductor quantum dots. This would result in significant efficiency increases in next generation solar cells.  While this kind of multi-exciton generation has been observed experimentally, there is considerable controversy over the efficiency of the effect in dots relative to bulk material.  Using a semi-empirical approach to study CdSe dots, we have shown that the rate of multiple carrier generation increases as dot size decreases for photons of the same relative energy.

More details on Center's website