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Program Highlights

Electrocaloric Effect of Perovskite High Entropy Oxide Films

Pb(Hf0.2Zr0.2Ti0.2Nb0.2X0.2)O3, a high-entropy perovskite, undergoes an entropy-driven phase transformation when X=Mn while X=Al always contains minor second phases in bulk ceramics.

Frustrated self-limiting assembly of trumpets

Triangular monomers with positive curvature in one direction and negative curvature in another assemble into trumpet shaped objects predicted to have precise self-limited lengths due to frustration-induced stress.

Active composite materials

Active composites obtained by merging   a   conventional   soft   matter actin    gel    with    energy    consuming microtubule   bundles   that   generate active   stresses   leads   to   emergent properties not present in the individual systems.

Exciton-Coupled Coherent Magnonsin a 2D Semiconductor

One exciting application of magnetic materials is the use of coherent magnonsas energy-efficient information carriers in spintronicsand magnonicsor as interconnects in hybrid quantum systems.

Ballistic Excitons and Surface Functionalization in a Superatomic Semiconductor

The transport of energy and information in semiconductors is limited by scattering between electronic carriers and lattice phonons, resulting in diffusive and  lossy  transport  that  curtails  all  semiconductor  technologies.

Atomic-scale origin of the low grain-boundary resistance in perovskite solid electrolyte Li0.375Sr0.4375Ta0.75Zr0.25O3

The main achievement of this research is revealing the atomic-scale origin of the low grain-boundary (GB) resistance in Li0.375Sr0.4375Ta0.75Zr0.25O3 (LSTZ0.75) perovskite solid electrolyte and providing insights on overcoming the ubiquitous bottleneck of high GB resistance in other oxide solid electrolytes.

Sugar-fueled Dissipative Living Materials

The  first  example  of  synthetic  living  material featuring   dissipative   behaviors   directly controlled  by  the  fuel  consumption  of  their constituent cells.

Leveraging the Polymer Glass Transition

A collaboration between the de Pablo, Rowan and Jaeger groups at the University of Chicago developed a novel class of suspensions with stimuli-responsive polymer particles to be able to transition reversibly between liquid to solid behavior in response to temperature,

Direct Synthesis and CVD of 2D MXenes

Novel chemical reactions enable scalable and atom-economic synthesis of two-dimensional metal carbides and nitrides (MXenes). These directly synthesized MXenes from the University of Chicago show excellent energy storage capacity for Li-ion intercalation.

Plant Leaf ELMs Undergo Shape Shifting Driven by External Stimuli

Plant/polymer composite materials have been fabricated. These  composite  materials  are  stimuli responsive  and  can  undergo  shape-shifting   behavior   in   response   to temperature or light. 

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