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Highlights

Co-based metal-organic frameworks as spin liquid candidates
Co-based metal-organic frameworks as spin liquid candidates
May 14, 2025
Big Idea: Quantum Leap

Co-based metal-organic frameworks as spin liquid candidates

Prof. Yiying Wu, Jos Heremans, Nandini Trivedi, Yuanming Lu (OSU), Sara Haravifard (Duke)

Researchers have created a new cobalt-based metal-organic framework that shows potential for hosting a Kitaev spin liquid. This material features cobalt ions in a honeycomb arrangement, linked together by benzoquinone, which creates a special type of magnetic frustration. By adjusting the linkers' chemical composition, the strength of the magnetic interactions can be varied. While magnetization tests indicated antiferromagnetic interactions, no spin ordering was found at low temperatures, highlighting this framework's potential in exploring spin liquid physics.
Upper left: A schematic of the Kitaev honeycomb model and its Hamiltonian.
Upper right: a two-spin flip operator creates a pair of Majorana excitations 𝑚 in the ground state. Lower left: the single-spin-flip structure factor 𝑆_1 does not show features of the Majorana excitations. Lower right: the two-spin-flip structure factor 𝑆_2^𝑧 shows sharp features that reflect the dispersion relation of the Majoranas.
Upper left: A schematic of the Kitaev honeycomb model and its Hamiltonian. Upper right: a two-spin flip operator creates a pair of Majorana excitations 𝑚 in the ground state. Lower left: the single-spin-flip structure factor 𝑆_1 does not show features of the Majorana excitations. Lower right: the two-spin-flip structure factor 𝑆_2^𝑧 shows sharp features that reflect the dispersion relation of the Majoranas.
May 14, 2025
Big Idea: Quantum Leap, Harnessing the Data Revolution

Sharp signatures of fractionalized excitations in Kitaev spin liquids

Prof. Nandini Trivedi, The Ohio State University

Researchers have theoretically shown that distinct signs of Majorana excitations can be found in the Kitaev honeycomb model when a perpendicular magnetic field is applied. These unique features appear in what are called two-spin-flip excitations. The findings suggest that techniques like nonlinear THz spectroscopy could help detect these signatures in materials that are being studied as spin liquids. This work advances the understanding of quantum matter in these complex systems.
Figure 1. (a) Schematic of BV center in hBN (b) Regions of exfoliated hBN containing BV centers created by scanned Ga ion-irradiation are visible in  hBN exfoliated onto a microwave waveguide on top of the sample (c)  Optically detected magnetic resonance of BV centers showing expected linear dispersion (magnetic field perpendicular to the plane) (d) optically detected FMR of YIG employing relaxometry of BVs by magnons.
Figure 1. (a) Schematic of BV center in hBN (b) Regions of exfoliated hBN containing BV centers created by scanned Ga ion-irradiation are visible in hBN exfoliated onto a microwave waveguide on top of the sample (c) Optically detected magnetic resonance of BV centers showing expected linear dispersion (magnetic field perpendicular to the plane) (d) optically detected FMR of YIG employing relaxometry of BVs by magnons.
May 14, 2025
Big Idea: Quantum Leap

Quantum Sensing of Spin Dynamics Using Boron-Vacancy Centers in Hexagonal Boron Nitride

P. Chris Hammel, Fengyuan Yang (OSU), Jyoti Katoch, Simranjeet Singh (CMU)

A recent study showcased how boron-vacancy centers in hexagonal boron nitride can be used for quantum sensing. These defects allow for the detection of weak magnetic fields through their spin-sensitive light emissions. The researchers demonstrated the capability to optically detect specific magnetic wave behaviors in materials like yttrium iron garnet. This work positions boron-vacancy centers as a flexible tool for exploring various magnetic phenomena in new material systems.
Figure 1. (a) Atomically clean WTe2/CGT interface. (b) Left: Generation of nonequilibrium spin accumulation with an out-of-plane spin polarization (𝝈_𝒛), when a charge current (𝐽) is applied along the a-axis of WTe2. Right: Concept of unconventional UMR in heterostructures, i.e., change of longitudinal resistance (𝑅_𝑈𝑀𝑅) depending on the relative orientation of out-of-plane magnetization (𝒎_𝒛) and spin polarization (𝝈_𝒛). (c) A schematic showing the measurement configuration to read the out-of-plane magnetic state of CGT employing 2-point longitudinal resistance (𝑅_𝑥𝑥). (d) UMR signal measured with +/- current. The step-like change in 2-point 𝑅_𝑥𝑥  is due to UMR switching sign when the current is reversed, with symmetric and antisymmetric components shown (lower panel).
Figure 1. (a) Atomically clean WTe2/CGT interface. (b) Left: Generation of nonequilibrium spin accumulation with an out-of-plane spin polarization (𝝈_𝒛), when a charge current (𝐽) is applied along the a-axis of WTe2. Right: Concept of unconventional UMR in heterostructures, i.e., change of longitudinal resistance (𝑅_𝑈𝑀𝑅) depending on the relative orientation of out-of-plane magnetization (𝒎_𝒛) and spin polarization (𝝈_𝒛). (c) A schematic showing the measurement configuration to read the out-of-plane magnetic state of CGT employing 2-point longitudinal resistance (𝑅_𝑥𝑥). (d) UMR signal measured with +/- current. The step-like change in 2-point 𝑅_𝑥𝑥 is due to UMR switching sign when the current is reversed, with symmetric and antisymmetric components shown (lower panel).
May 14, 2025
Big Idea: Quantum Leap

Discovery of a New Type of Magnetoresistance

Simranjeet Singh (CMU), Jyoti Katoch (CMU), Jinwoo Hwang (OSU)

A new type of magnetoresistance called unidirectional magnetoresistance (UMR) has been discovered in a study that combines a topological semimetal (WTe₂) with a ferromagnetic semiconductor (Cr₂Ge₂Te₆). This phenomenon involves changes in resistance linked to magnetization reversal and spin interactions. The findings highlight how the unique properties of these materials can create distinct resistance states, which could be valuable for developing more advanced magnetic memory devices.
A responsive living material prepared by diffusion reveals extracellular enzyme activity of cyanobacteria
A responsive living material prepared by diffusion reveals extracellular enzyme activity of cyanobacteria
May 12, 2025
Big Idea: Recyclable Plastics and Alternative Materials, Synthetic Materials Biology, Understanding the Rules of Life

A responsive living material prepared by diffusion reveals extracellular enzyme activity of cyanobacteria

Lisa Tang, Nathan Soulier, Rebecca Wheeler, Jonathan K. Pokorski, James W. Golden, Susan S. Golden, Jinhye Bae: UC San Diego

One of the research goals of UCSD MRSEC IRG2 included developing shape-shifting materials driven by asymmetric forces. In a recent effort, the MRSEC team demonstrated an ELM capable of shape-shifting driven by both a temperature stimulus and enzymatic mediated partial degradation of the composite material.
IRG1: Modification of Plasmonic Nanocrystals with Sterically-Encumbered Isocyanide Ligands
IRG1: Modification of Plasmonic Nanocrystals with Sterically-Encumbered Isocyanide Ligands
May 12, 2025
Big Idea: Growing Convergence Research, Harnessing the Data Revolution, Quantum Leap

IRG1: Modification of Plasmonic Nanocrystals with Sterically-Encumbered Isocyanide Ligands

Joshua Figueroa, Tod Pascal, Shaowei Li, Andrea Tao: UC San Diego

A recent study revealed that m-terphenyl isocyanide ligands have different orientations when bonded to gold and silver surfaces—vertical on gold and flat on silver. This finding is important as it helps understand how surface ligands affect the properties of plasmonic nanoparticles. The research could lead to the development of new types of patterned nanoparticles, which would facilitate new self-assembly techniques, bridging the gap between inorganic materials and proteins.
Novel Electronic Bands in a Supermoiré Lattice
Novel Electronic Bands in a Supermoiré Lattice
May 7, 2025
Big Idea: Quantum Leap

Novel Electronic Bands in a Supermoiré Lattice

Shih, Han (Rice), Khalaf (Harvard), Giustino, Robinson (Penn State), Li

Super-moiré patterns identified in WSe2 bilayer with large twist angles. While moiré superlattices in graphene and transition metal dichalcogenide (TMD) bilayers with small twist angles are known to exhibit flat bands and host exotic correlated phases, strong lattice reconstruction in these systems poses challenges. In contrast, large-angle bilayers are structurally robust but typically considered electronically decoupled. Here, we discover robust super-moiré patterns emerging near a large commensurate angle, combining the advantages of both regimes—structural stability with flat electronic bands. This work expands moiré twistronics and flat-band quantum physics into the large twist-angle regime.
Independently Tunable Flat Bands and Correlations in a Graphene Double Moiré
Independently Tunable Flat Bands and Correlations in a Graphene Double Moiré
May 7, 2025
Big Idea: Quantum Leap

Independently Tunable Flat Bands and Correlations in a Graphene Double Moiré

Tutuc, MacDonald, Zheng, Taniguchi, Watanabe (NIMS, Japan)

Novel double moiré system realized in a four-layer twist- controlled graphene structure. These double moiré twist-controlled structure goes beyond the single moiré structures generally investigated in twisted bilayer graphene or transition metal dichalecogenides. The results show that demonstrate that electronic confinement in multilayer graphene stacks can be compactly realized by changing the twist angles, in contrast to traditional band engineering that employ dissimilar materials. Furthermore, near the magic angle the flat bands host correlated insulators, which suggests that the proximity of one flat band does not suppress the correlated insulating states in the other flat band.
By exciting an ITO nanocrystal with near-infrared (NIR) light, we generate heat that can be passed from the nanocrystal to its environment. We have tracked this process using probes placed at a nanocrystal’s surface and in its surrounding solvent that show colorimetric changes on heating.
By exciting an ITO nanocrystal with near-infrared (NIR) light, we generate heat that can be passed from the nanocrystal to its environment. We have tracked this process using probes placed at a nanocrystal’s surface and in its surrounding solvent that show colorimetric changes on heating.
May 7, 2025
Big Idea: Growing Convergence Research, Quantum Leap

Converting Light into Heat using Plasmonic Metal Oxide Nanocrystals

Sean T. Roberts, Carlos R. Baiz, Delia J. Milliron, & Thomas M. Truskett

Metal Oxide nanocrystals that incorporate dopants (impurities) can display intense absorption bands known as localized surface plasmon resonances (LSPRs) that can transduce light into heat. Using a series of time-resolved measurements with femtosecond resolution together with a theoretical heat transfer model, we have quantified timescales over which tin-doped indium oxide (ITO) nanocrystals heat their environment following light absorption.
A Light-Dependent Synthetic Cortex
A Light-Dependent Synthetic Cortex
May 7, 2025
Big Idea: Understanding the Rules of Life

A Light-Dependent Synthetic Cortex

Ahmed Sihorwala, Unyime Effiong, and Brian Belardi. UT Austin

Here, we developed a method to generate a synthetic cortex at the membrane of synthetic cells upon blue light illumination. This is important since it allow us to control the mechanical properties of synthetic cells reversibly. When incorporated into a synthetic tissue, this method would enable mechanical patterning and defining the 3D morphology of tissue with light.