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The Northwestern University MRSEC supports a diverse suite of international collaborations and outreach activities. For example, the Center provided support for 10 students and postdoctoral research associates to attend the 9th International Conference of the African Materials Research Society (AMRS) on December 11-14, 2017 in Gaborone, Botswana.

A novel category of hydrogel material has been developed (Hawker, Kramer)that form spontaneously in  water through complexation of polyelectrolyte endblocks of PEG-based triblock polyelectrolytes—inspired by Waite’s mussel adhesion studies. SANS (Kramer) and dynamic nuclear polarization (DNP)-enhanced NMR; (Han) reveal that these complexes form dense, yet fluid, coacervate core domains with significant ordering.

Joining different materials can lead to all kinds of breakthroughs. In electronics, this produces heterojunctions — the most fundamental components in solar cells and computer chips. The smoother the seam between two materials, the better the electronic devices will function.

The properties of glasses – disordered, amorphous materials – can be hard to predict because of this lack of long-range order and the associate properties of crystal symmetry.  Work in this IRG has developed two fundamental descriptors to describe glass properties.  The first of these – softness – is a machine-learning derived descriptor that characterizes structural defects in glasses and predicts rearrangements or yield that will occur in disordered materials in response to applied loads. The second – excess entropy – is a thermodynamic quantity that is a simple function of that describes the deviation of atomic arrangements from what would be predicated from ideal gas theory.

Background: The JHU MRSEC conducts extensive K-12 educational outreach programs aimed at promoting interest in and awareness of the importance of modern materials research. High school students from the greater Baltimore area receive four-week internships each July to conduct research in the laboratories of the JHU MRSEC. The students are mentored by Center faculty, and also work closely with graduate students and/or postdoctoral fellows.  At the end of the month, each student gives a 20-minute talk describing his/her project at a symposium

Sub-nanometer probes of surfaces provide important information about chemical and physical properties of materials at atomic level.  Microwave microscopy (left) is used to study materials properties at GHz (109 sec-1). This is the frequency range relevant for computers and cell phones, for which the materials are being explored. We show for the first time that one can image atoms at this frequency (right).

Background: A bar magnet has two poles, denoted as +1 and -1 magnetic charges.  Patterned structures consist of many magnets (Fig. 1), where the square array (Fig. 1a) does not, whereas the honeycomb (Fig. 1b) has, net magnetic charges (or magnetic monopoles).  Under a magnetic field these local magnetic monopoles will move (Fig. 1c).  This latter structure is called “spin ice”, because it has a large number of nearly degenerate configurations.