Skip to main content

Highlights

Schematic diagram showing the nanoemulsion system and thermally-induced surfactant displacement. By displacing charged surfactants we can change the droplet-droplet interactions and induce gelation.
Schematic diagram showing the nanoemulsion system and thermally-induced surfactant displacement. By displacing charged surfactants we can change the droplet-droplet interactions and induce gelation.
Jun 10, 2020
Big Idea: Quantum Leap

Thermally Induced Surfactant Displacement to Induce Colloidal Gelation

Patrick Doyle

Doyle has discovered a new way to thermally-induce gelation of nanoemulsions. They developed a platform wherein colloidal gelation is controlled by tuning repulsive interactions.
(a) Functional filament is quickly fed through a short hot end to print a 3D star structure. (b) Filament surface heating allows the outer cladding to be heated above its Tg, while the inner core of the filament is maintained at a lower temperature, preserving its structure. (c, d) Cross-sectional images of fused microstructured filaments, which can be further shaped into 3D cm-scale objects. (e) Schematic of a printed airplane wing with light-emitting and photodetecting functionalities for detecting structural defects. The top and bottom print layers of the airplane wing are light-emitters, and the middle 3 layers are photodetectors. (f) Photograph of printed airplane wing; scale bar, 2 cm. The locations of structural defects can be determined by measuring the magnitude of the photocurrent after defects are made and correlating the photocurrent magnitude with the severed length of the photodetecting filament.
(a) Functional filament is quickly fed through a short hot end to print a 3D star structure. (b) Filament surface heating allows the outer cladding to be heated above its Tg, while the inner core of the filament is maintained at a lower temperature, preserving its structure. (c, d) Cross-sectional images of fused microstructured filaments, which can be further shaped into 3D cm-scale objects. (e) Schematic of a printed airplane wing with light-emitting and photodetecting functionalities for detecting structural defects. The top and bottom print layers of the airplane wing are light-emitters, and the middle 3 layers are photodetectors. (f) Photograph of printed airplane wing; scale bar, 2 cm. The locations of structural defects can be determined by measuring the magnitude of the photocurrent after defects are made and correlating the photocurrent magnitude with the severed length of the photodetecting filament.
Tunable Persistent Random Walk in Swimming
Tunable Persistent Random Walk in Swimming
Jun 10, 2020
Big Idea: Quantum Leap

Tunable Persistent Random Walk in Swimming

A. Izzet, P. Moerman, P. Gross, J. Groenewold, A. D. Hollingsworth, J. Bibette, and J. Brujic, New York University

Here we explain the molecular engine of droplet motion that gives rise to their persistent random walk. This result allows us to tune their swimming speed and turning frequency over a range that is much broader than that of solid active particles.
A hydrogen-bonded framework toolkit for molecular structure determination
A hydrogen-bonded framework toolkit for molecular structure determination
Jun 10, 2020
Big Idea: Quantum Leap

A hydrogen-bonded framework toolkit for molecular structure determination

Y. Li, S. Tang, A. Yusov, J. Rose, A. Borrfors, C. T. Hu, M. D. Ward

MRSEC investigators reported that a versatile toolkit of guanidinium organosulfonate hydrogen-bonded host frameworks can form inclusion compounds with complex “stubborn” molecules that cannot be crystallized or form suitable single crystals for X-ray diffraction analysis by themselves, enabling determination of their molecular structure.
A general framework for nanoscale electromagnetism
A general framework for nanoscale electromagnetism
Jun 10, 2020
Massachusetts Institute of Technology

A general framework for nanoscale electromagnetism

John D. Joannopoulos and Marin Soljačić, Massachusetts Institute of Technology

The d parameters are a convenient parametrization for surface-related, quantum corrections. We  establish  a  systematic  approach  to measure the d parameter dispersion of a general two-material interface.
Voltage Control of Optical Properties by Ionic Gating
Voltage Control of Optical Properties by Ionic Gating
Jun 10, 2020
Massachusetts Institute of Technology

Voltage Control of Optical Properties by Ionic Gating

Geoffrey Beach, Massachusetts Institute of Technology

Using a simple device structure, it has been shown that electrical control of optical properties can be achieved through electrochemical hydrogen gating, sourced from moisture in the air.
Building Enduring Pathways in STEM: Incorporating Traditional Ways of Knowing in Materials Research
Building Enduring Pathways in STEM: Incorporating Traditional Ways of Knowing in Materials Research
Jun 9, 2020
Harvard University

Building Enduring Pathways in STEM: Incorporating Traditional Ways of Knowing in Materials Research

David A. Weitz (Physics and AppPhy) and Thiagarajan Soundappan (Navajo Tech Univ, Chem)

This unique partnership between Navajo Technical University and the Harvard MRSEC builds enduring pathways for undergraduate Native American students into STEM by including traditional Navajo  perspectives and methods of scientific inquiry in materials science research and education.
Shape-Shifting Lattices via Multimaterial 4D Printing
Shape-Shifting Lattices via Multimaterial 4D Printing
Jun 9, 2020
Harvard University

Shape-Shifting Lattices via Multimaterial 4D Printing

L. Mahadevan (Applied Math) & J.A. Lewis (MatSci &  BioEng)

A team at the Harvard MRSEC led by Lakshminarayanan Mahadevan and Jennifer A. Lewis has created shape-shifting lattices by combining predictive design and multimaterial 4D printing.
Figure: Secondary electron image of a microfabricated metal/polymer multilayer structure. A conventional gallium FIB would take days to remove such a large amount of material.  Images like these provide input for three dimensional reconstructions of materials structure.
Figure: Secondary electron image of a microfabricated metal/polymer multilayer structure. A conventional gallium FIB would take days to remove such a large amount of material. Images like these provide input for three dimensional reconstructions of materials structure.
May 27, 2020
University of Pennsylvania

Focused Ion Beam / Scanning Electron Microscope: TESCAN S8000X

Eric A. Stach, Mark Allen, Marija Drndic and Deep Jariwala, University of Pennsylvania

In the Fall of 2019, the LRSM installed a uniquely equipped focused ion beam / scanning electron microscope from the TESCAN corporation. The instrument has a high flux xenon source, allowing rapid sample removal. It is equipped with two novel accessories, a cryogenic transfer system and a time-of-flight secondary ion mass spectrometer (ToF-SIMS). These two capabilities will allow the development of novel methods for the microanalytical characterization of soft matter and soft/hard matter interfaces.
Adriana Santiago-Ruiz (Middle): Explaining details of the materials science experiment to the high school participants at “Experimenta con PREM”
Adriana Santiago-Ruiz (Middle): Explaining details of the materials science experiment to the high school participants at “Experimenta con PREM”
May 27, 2020
University of Pennsylvania

Experimenta con PREM

Mark Licurse & Ashley Wallace, University of Pennsylvania

“Experimenta con PREM” is a summer high school program organized by PREM-UPR (Univ. of Puerto Rico [PR]) faculty. Led by Wallace and Licurse, Penn participates annually by creating workshops and staffing those workshops with LRSM post-docs and grad students. This year at Penn, our volunteer facilitators (grad students Genesis Quiles-Galarza and Adriana Santiago-Ruiz) designed a series of materials science focused experiments and demos for 29 high school students.